"GROWTH AND CHARACTERIZATION STUDIES OF PURE AND Mg2+ DOPED ZINC HYDROGEN PHOSPHATE CRYSTALS"

Document Type : Primary Research paper

Authors

Dept. of Physics, Nehru Institute of Engineering and Technology, Coimbatore, Tamilnadu, India

Abstract

Zinc hydrogen phosphate (ZHP) and magnesium doped zinc hydrogen phosphate (MZHP)
crystals are grown in silica gel medium with silica gel technique by the process of diffusion
using different gel densities and various concentrations of orthoposphoric acid and supernatant
solutions. The grown crystals were characterized by powder X – ray diffraction (PXRD) studies,
whereas from single crystal X-ray diffraction (SXRD) the crystal system comes out to be
orthorhombic. Fourier transform infrared spectroscopic (FTIR) studies signifies the presence of
phosphate (PO4)2- group and water of crystallization. Thermogravimetric analysis is undertaken
to study the thermal stability of the grown crystals. Kurtz powder technique is employed to
confirm their non – linear optic (NLO) behavior. The study of UV absorption spectra reveals that
the value of band gap energy decreased slightly as the concentration of magnesium increased.

Keywords


Volume 12, Issue 1
International virtual conference on Newer Trends and Innovation in Nanotechnology Materials Science . Science and Technology
March 2021
Pages 478-492